Laser-enhanced hydrogen production: designing a PEC cell photoanode with an exclusive dye material for superior efficiency

Sally A. Al-Ani, Mohamed K. Dhahir

Abstract


In the pursuit of efficient and sustainable hydrogen production, photoelectrochemical (PEC) cells offer a promising route for solar-to-hydrogen conversion. This study explores the innovative use of laser illumination to enhance the performance of PEC cell photoanodes, focusing on the fabrication of a distinct photoanode incorporating the exclusive dye material (Epolight™ 1178). By employing lasers with the assistance of a UV source as an alternative to conventional solar light, the energy absorption and catalytic activity of the photoanodes were significantly improved, leading to higher hydrogen generation rates. The photoanode’s design harnesses the power of the multiple layers to control the absorption of the photoanode to encompass the UV, VIS, and NIR regions.  Then, by utilizing this ability to match the incident light's wavelength with the materials' absorption peaks which leads to amazing and exceptional results. Photoelectrochemical measurements were carried out by linear sweep voltammetry in the dark and under illumination condition AM 1.5 G of 100 mW/cm2. Comparative analysis between laser-illuminated and traditional light-illuminated systems demonstrates a notable increase in hydrogen production efficiency in the laser-driven setup from 8.2% to 33.2%. This research highlights the potential of laser-assisted PEC technology as a pathway to overcoming the limitations of traditional solar energy systems, contributing to advancements in renewable hydrogen production.

 

Received: 06 October 2024

Accepted: 20 November 2024

Published: 27 November 2024


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References


G. Zuher, W. J. Aziz, and R. S. Sabry, “Producing Hydrogen Energy Using Cr2O3-TiO2 Nanocomposite with Animal (Chitosan) Extract via Photocatalaysis,” Ibn AL-Haitham Journal For Pure and Applied Sciences, vol. 35, no. 4, 2022, doi: 10.30526/35.4.2853.

M. G. C. Zoontjes, “Visible-light-induced water splitting on a chip,” University of Twente, Enschede, The Netherlands, 2015. doi: 10.3990/1.9789036538954.

M. Grätzel, “Photoelectrochemical cells,” Nature, vol. 414, no. 6861, pp. 338–344, Nov. 2001, doi: 10.1038/35104607.

M. B. Costa, M. A. de Araújo, M. V. de L. Tinoco, J. F. de Brito, and L. H. Mascaro, “Current trending and beyond for solar-driven water splitting reaction on WO3 photoanodes,” 2022. doi: 10.1016/j.jechem.2022.06.003.

Zainab K. Ali and Mazin A. Mahdi, “Preparation of Silicon Nanowires Photocathode for Photoelectrochemical Water Splitting,” Iraqi Journal of Physics, vol. 20, no. 4, 2022, doi: 10.30723/ijp.v20i4.1070.

S. Cho, J. W. Jang, K. H. Lee, and J. S. Lee, “Research update: Strategies for efficient photoelectrochemical water splitting using metal oxide photoanodes,” APL Mater, vol. 2, no. 1, 2014, doi: 10.1063/1.4861798.

A. TROVARELLI, “Catalytic Properties of Ceria and CeO 2 -Containing Materials,” Catalysis Reviews, vol. 38, no. 4, pp. 439–520, Nov. 1996, doi: 10.1080/01614949608006464.

E. Kusmierek, “A CeO2 semiconductor as a photocatalytic and photoelectrocatalytic material for the remediation of pollutants in industrial wastewater: A review,” 2020. doi: 10.3390/catal10121435.

D. Channei, A. Nakaruk, S. Phanichphant, P. Koshy, and C. C. Sorrell, “Cerium Dioxide Thin Films Using Spin Coating,” J Chem, Jan. 2013, doi: 10.1155/2013/579284.

R. S. Sachit, “Solar cells based on inkjet-printed layer polymer,” in Journal of Physics: Conference Series, 2021. doi: 10.1088/1742-6596/2114/1/012026.

R. Zamiri et al., “Dielectrical properties of CeO2 nanoparticles at different temperatures,” PLoS One, vol. 10, no. 4, 2015, doi: 10.1371/journal.pone.0122989.

Y. Tong, W. Liu, C. Li, X. Liu, J. Liu, and X. Zhang, “A metal/semiconductor contact induced Mott-Schottky junction for enhancing the electrocatalytic activity of water-splitting catalysts,” 2022. doi: 10.1039/d2se01355j.

F. Mikaeili, T. Gilmore, and P.-I. Gouma, “Photochemical Water Splitting via Transition Metal Oxides,” Catalysts, vol. 12, no. 11, p. 1303, Oct. 2022, doi: 10.3390/catal12111303.

S. S. Martín, M. J. Rivero, and I. Ortiz, “Unravelling the mechanisms that drive the performance of photocatalytic hydrogen production,” 2020. doi: 10.3390/catal10080901.

M. C. Crisan, M. Teodora, and M. Lucian, “Copper nanoparticles: Synthesis and characterization, physiology, toxicity and antimicrobial applications,” 2022. doi: 10.3390/app12010141.

H. S. Cho, T. Kodama, N. Gokon, S. Bellan, and J. K. Kim, “Development of synthesis and fabrication process for mn-ceo2 foam via two-step water-splitting cycle hydrogen production†,” Energies (Basel), vol. 14, no. 21, 2021, doi: 10.3390/en14216919.

M. B. Gawande et al., “Cu and Cu-Based Nanoparticles: Synthesis and Applications in Catalysis,” Chem Rev, vol. 116, no. 6, pp. 3722–3811, Mar. 2016, doi: 10.1021/acs.chemrev.5b00482.

P. Zhang, H. Liu, and X. Li, “Photo-reduction synthesis of Cu nanoparticles as plasmon-driven non-semiconductor photocatalyst for overall water splitting,” Appl Surf Sci, vol. 535, 2021, doi: 10.1016/j.apsusc.2020.147720.

F. G. Hamzah and H. R. Humud, “Signature of plasmonic nanostructures synthesised by electrical exploding wire technique on surface-enhanced raman scattering,” Iraqi Journal of Science, vol. 62, no. 1, 2021, doi: 10.24996/ijs.2021.62.1.16.

M. Watanabe, “Dye-sensitized photocatalyst for effective water splitting catalyst,” 2017. doi: 10.1080/14686996.2017.1375376.

M. Raffi et al., “Investigations into the antibacterial behavior of copper nanoparticles against Escherichia coli,” Ann Microbiol, vol. 60, no. 1, 2010, doi: 10.1007/s13213-010-0015-6.

D. Han, Z. Meng, D. Wu, C. Zhang, and H. Zhu, “Thermal properties of carbon black aqueous nanofluids for solar absorption,” Nanoscale Res Lett, vol. 6, no. 1, p. 457, Jul. 2011, doi: 10.1186/1556-276X-6-457.

A. Kaliyaraj Selva Kumar, Y. Zhang, D. Li, and R. G. Compton, “A mini-review: How reliable is the drop casting technique?,” 2020. doi: 10.1016/j.elecom.2020.106867.

M. Wu, A. H. Caldwell, and A. Allanore, “Surface Tension of High Temperature Liquids Evaluation with a Thermal Imaging Furnace,” 2019, pp. 33–41. doi: 10.1007/978-3-030-06143-2_4.

P. Ravi and J. Noh, “Photocatalytic Water Splitting: How Far Away Are We from Being Able to Industrially Produce Solar Hydrogen?,” 2022. doi: 10.3390/molecules27217176.

D. Girija, H. S. B. Naik, cn Sudhamani, and B. V. Kumar, “Cerium Oxide Nanoparticles-a Green, Reusable, and Highly Efficient Heterogeneous Catalyst for the Synthesis of Polyhydroquinolines Under Solvent-free Conditions,” vol. 3, pp. 373–382, 2011.

Y. Fan, D. Li, M. Deng, Y. Luo, and Q. Meng, “An overview on water splitting photocatalysts,” Frontiers of Chemistry in China, vol. 4, no. 4, 2009, doi: 10.1007/s11458-009-0100-1.

M. C. Crisan, M. Teodora, and M. Lucian, “Copper Nanoparticles: Synthesis and Characterization, Physiology, Toxicity and Antimicrobial Applications,” Applied Sciences, vol. 12, no. 1, p. 141, Dec. 2021, doi: 10.3390/app12010141.

J. Li and N. Wu, “Semiconductor-based photocatalysts and photoelectrochemical cells for solar fuel generation: A review,” 2015. doi: 10.1039/c4cy00974f.

S. Cho, J.-W. Jang, K.-H. Lee, and J. S. Lee, “Research Update: Strategies for efficient photoelectrochemical water splitting using metal oxide photoanodes,” APL Mater, vol. 2, no. 1, Jan. 2014, doi: 10.1063/1.4861798.

S. Bai et al., “An Integrating Photoanode of WO3/Fe2O3 Heterojunction Decorated with NiFe-LDH to Improve PEC Water Splitting Efficiency,” ACS Sustain Chem Eng, vol. 6, no. 10, 2018, doi: 10.1021/acssuschemeng.8b02267.

W. Ismail, G. Ibrahim, M. A. Habib, O. K. Alduaij, M. Abdelfatah, and A. El-Shaer, “Advancement of Physical and Photoelectrochemical Properties of Nanostructured CdS Thin Films toward Optoelectronic Applications,” Nanomaterials, vol. 13, no. 11, 2023, doi: 10.3390/nano13111764.

S. Soni et al., “Electronic Structure and Room Temperature Ferromagnetism in Gd‐doped Cerium Oxide Nanoparticles for Hydrogen Generation via Photocatalytic Water Splitting,” Global Challenges, vol. 3, no. 5, 2019, doi: 10.1002/gch2.201800090.

M. L. Gaur, P. P. Hankare, K. M. Garadkar, S. D. Delekar, and V. M. Bhuse, “CdSe thin films: morphological, optoelectronic and photoelectrochemical studies,” Journal of Materials Science: Materials in Electronics, vol. 25, no. 1, pp. 190–195, Jan. 2014, doi: 10.1007/s10854-013-1572-9.

Y. Huang, H. Yang, X. Lu, M. Chen, and W. Shi, “Near infrared-driven photocatalytic overall water splitting: Progress and perspective,” 2024. doi: 10.1016/S1872-2067(23)64594-2.

M. A. Hamid, Y. Zengin, and I. Boz, “Surface Plasmon Resonance-enhanced photocatalytic water-splitting for improved visible-light-driven H2 generation using Ag-modified twin crystal Cd0.5Zn0.5S photocatalysts,” Catal Commun, vol. 187, 2024, doi: 10.1016/j.catcom.2024.106841.

S. Khanam and S. K. Rout, “Plasmonic Metal/Semiconductor Heterostructure for Visible Light-Enhanced H 2 Production,” ACS Omega, vol. 7, no. 29, pp. 25466–25475, Jul. 2022, doi: 10.1021/acsomega.2c02459.

S. Wang et al., “Boosting photoelectrochemical water splitting by Au@Pt modified ZnO/CdS with synergy of Au-S bonds and surface plasmon resonance,” J Catal, vol. 408, 2022, doi: 10.1016/j.jcat.2022.03.003.

L. Liu, C. Zhao, J. Xu, and Y. Li, “Integrated CO2 capture and photocatalytic conversion by a hybrid adsorbent/photocatalyst material,” Appl Catal B, vol. 179, 2015, doi: 10.1016/j.apcatb.2015.06.006.

Y. Qiu et al., “Current progress in developing metal oxide nanoarrays-based photoanodes for photoelectrochemical water splitting,” Sci Bull (Beijing), vol. 64, no. 18, pp. 1348–1380, Sep. 2019, doi: 10.1016/j.scib.2019.07.017.




DOI: http://dx.doi.org/10.21622/resd.2024.10.2.1050

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Copyright (c) 2024 Sally A. Al-Ani, Mohamed K. Dhahir


Renewable Energy and Sustainable Development

E-ISSN: 2356-8569

P-ISSN: 2356-8518

 

Published by:

Academy Publishing Center (APC)

Arab Academy for Science, Technology and Maritime Transport (AASTMT)

Alexandria, Egypt

resd@aast.edu