Computational simulation study of the impact of isotropic GDL thermal conductivity on PEMFC characteristics

Mahmut Kaplan

Abstract


The technical capability of proton exchange membrane fuel cell (PEMFC) offers an encouraging solution to produce sustainable and clean power. The pivotal part of the PEMFCs is the gas diffusion layer (GDL) which performs critical roles in providing a pathway for reactant and product. GDL electrically connects the catalyst layer to the current collector and conducts heat generated in the electrochemical reactions. The thermal conductivity as a transport property of the GDL affects heat transfer across the cell and the overall performance. In the current work, the impact of the isotropic GDL thermal conductivity ranging 1-100 W/mK at 0.4 and 0.6 V on the cell efficiency is studied computationally using ANSYS Fluent PEMFC module. The results indicate that an increase in the GDL thermal conductivity enhances the fuel cell current density considerably up to 20 W/mK and then the impact of the GDL thermal conductivity on the performance diminishes at 0.4 and 0.6 V. The power function provided a good fit with the calculated data. The maximum current density of 1.38 A/cm2 with the more homogeneous temperature distribution and lower temperature across PEMFC is obtained at 100 W/mK. Moreover, oxygen consumption and water production augments with higher thermal conductivity, especially the regions above the cathode current collector ribs.

 

Received: 09 September 2023

Acepted: 29 November 2023

Published: 20 December


Keywords


PEMFC, GDL, Thermal conductivity, Heat transfer, Performance; CFD.

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References


Alcántara A. M., Morán L. G., Pino J., Guerra J. and Iranzo A., “Effect of the gas diffusion layer design on the water management and cell performance of a PEM fuel cell,” Processes, vol. 10, no. 7, 1395, 2022. https://doi.org/10. 3390/pr10071395

Alhazmi N., Ingham D. B., Ismail M. S., Hughes K. J., Ma L. and Pourkashanian M., “Effect of the anisotropic thermal conductivity of GDL on the performance of PEM fuel cells,” International Journal of Hydrogen Energy, vol. 38, no. 1, pp. 603-611, 2013. https://doi.org/10.1016/j.ijhydene.2012.07.007

ANSYS FLUENT 15.0 Fuel Cell Modules Manual, ANSYS, Inc., 2013

Athanasaki G., Jayakumar A. and Kannan A. M., “Gas diffusion layers for PEM fuel cells: materials, properties and manufacturing - a review,” International Journal of Hydrogen Energy, vol. 48, no. 6, pp. 2294-2313, 2023. https://doi.org/10.1016/j.ijhydene.2022.10.058

Barbir F., “PEM fuel cells: theory and practice,” Elsevier/Academic Press, 2013.

Biyikoglu A. and Alpat C. O., “Parametric study of a single cell proton exchange membrane fuel cell for a bundle of straight gas channels,” Gazi University Journal of Science, vol. 24, no. 4, pp. 883–899, 2011.

Chowdhury P. R., Vikram A., Phillips R. K. and Hoorfar M., “Measurement of effective bulk and contact resistance of gas diffusion layer under inhomogeneous compression - part II: thermal conductivity,” Journal of Power Sources, vol. 320, pp. 222-230, 2016. https: //doi.org/10.1016/j.jpowsour.2016.04.112

Cindrella L., Kannan A. M., Lin J. F., Saminathan K., Ho Y., Lind C. W. and Wertz J., “Gas diffusion layer for proton exchange membrane fuel cells - a review,” Journal of Power Sources, vol. 194, no. 1, pp. 146-160, 2009. https://doi.org/10.1016/j.jpowsour.2009. 04.005

Dincer I., “Hydrogen and Fuel Cell Technologies for Sustainable Future,” Jordan Journal of Mechanical and Industrial Engineering, vol. 2, no. 1, pp. 1-14, 2008.

He G., Yamazaki Y. and Abudula A., “A three-dimensional analysis of the effect of anisotropic gas diffusion layer(GDL) thermal conductivity on the heat transfer and two-phase behavior in a proton exchange membrane fuel cell (PEMFC),” Journal of Power Sources, vol. 195, no. 6, pp. 1551-1560, 2010. https://doi.org/10.1016/j.jpowsour.2009.

059

Kahveci E. E. and Taymaz I.., “Assessment of single-serpentine PEM fuel cell model developed by computational fluid Dynamics,” Fuel, vol. 217, pp. 51-58, 2018. https://doi.org/ 10.1016/j.fuel.2017.12.073

Kaplan M., “Numerical investigation of influence of cross-sectional dimensions of flow channels on PEM fuel cell performance,” Journal of Energy Systems, vol. 5, no. 2, pp. 137–148, 2021. https://doi.org/10.30521/jes. 871018

Kaplan M., “A numerical parametric study on the impacts of mass fractions of gas species on PEMFC performance,” Engineering and Technology Quarterly Reviews, vol. 5, no. 2, pp. 38-45, 2022.

Kaplan, M., “Three-dimensional CFD analysis of PEMFC with different membrane thicknesses,” Renewable Energy and Sustainable Development, vol. 8, no. 2, 45-51, 2022.

Okonkwo P. C. and Otor C., “A review of gas diffusion layer properties and water management in proton exchange membrane fuel cell system,” International Journal of Energy Research, vol. 45, no. 3, pp. 3780-3800, 2021. https://doi.org/10.1002/er.6227

Omrani R. and Shabani B., “Review of gas diffusion layer for proton exchange membrane-based technologies with a focus on unitised regenerative fuel cells,” International Journal of Hydrogen Energy, vol. 44, no. 7, pp. 3834-3860, 2019. https://doi.org/10.1016/ j.ijhydene.2018.12.120

Ozden A., Shahgaldi S., Li X. and Hamdullahpur F., “A review of gas diffusion layers for proton exchange membrane fuel cells—With a focus on characteristics, characterization techniques, materials and designs”. Progress in Energy and Combustion Science, Vol. 74, 2019, 50-102.

Spiegel C. PEM fuel cell modeling and simulation using MATLAB. Amsterdam: Elsevier; 2008.

Turkmen A. C., Andaluz M. E., Celik C., Sunden B., Soyhan H. S., “Impact of the temperature variation on the thermal conductivity of gas diffusion layers for polymer electrolyte fuel cells,” Fuel, vol. 345, 128097, 2023. https://doi.org/10.1016/j.fuel. 2023.128097

Wang L., Husar A., Zhou T., and Liu H., “A parametric study of PEM fuel cell performances,” International Journal of Hydrogen Energy, vol. 28 no. 11, pp. 1263–1272., 2003. https://doi.org/10.1016/S0360-3199(02)00284-7

Zamel N. and Li X., “Effective transport properties for polymer electrolyte membrane fuel cells e with a focus on the gas diffusion layer,” Progress in Energy and Combustion Science, vol. 39, no. 1, pp. 111-146, 2013. https://doi.org/10.1016/j.pecs.2012.07.002




DOI: http://dx.doi.org/10.21622/resd.2023.09.2.042

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Copyright (c) 2023 Mahmut Kaplan


Renewable Energy and Sustainable Development

E-ISSN: 2356-8569

P-ISSN: 2356-8518

 

Published by:

Academy Publishing Center (APC)

Arab Academy for Science, Technology and Maritime Transport (AASTMT)

Alexandria, Egypt

resd@aast.edu